Per- and Polyfluoroalkyl Substances (PFAS) in Long Island

This project aims to document the concentrations of different PFAS that have been measured throughout Long Island’s groundwater

Overview on Per- and Polyfluoroalkyl Substances (PFAS)

What are PFAS?

Per- and polyfluoroalkyl substances (PFAS) are a group of thousands of man-made chemicals with many carbon and fluorine (C-F) bonds. PFAS are extremely resistant to most surfactant activity and degradation processes which makes them desirable for industrial and manufacturing products.

PFAS are ubiquitously present all around us, from household products like non-stick cookware and utensils, food packaging, polishes, cleaning agents, creams, stain-resistant and waterproof clothes, textiles, carpets, upholstery, and paper to industrial products like firefighting foams, pesticide formulations, ski wax, lubricating oils, and even drugs and medical devices (Agency for Toxic Substances and Disease Recovery or ATSDR, 2020; European Environment Agency or EEA, 2019; Toxic-Free Future or TFF, 2018).

The same attributes that make PFAS desirable for use in industrial and commercial products render them toxic and difficult to remove from the environment and from the human body. Their inability to break down and their capacity to bioaccumulate has earned PFAS the label of “forever chemicals.”

How are humans exposed to PFAS?

The use and subsequent degradation over the lifetime of industrial and household products that contain PFAS leads to the release of PFAS into the environment which keep on recirculating through the environment. Humans are exposed to PFAS are through ingestion of contaminated drinking water and seafood, inhalation of contaminated indoor air, and contact with contaminated products (USEPA, 2019; TFF, 2018).

Why are PFAS toxic?

Epidemiological studies have shown a potential link between PFAS exposure and thyroid disease, high cholesterol, ulcerative colitis, kidney cancer, testicular cancer, pregnancy-induced hypertension, and others (EEA, 2019; TFF, 2018). The impacts on unborn infants include delayed mammary gland development, reduced response to vaccines, and lower birth weight (EEA, 2019).

Case Study: Long Island

In 2019, the Environmental Working Group (EWG) published  a map of PFAS contaminated sites across the U.S.  which included numerous sites in New York State (NYS). The focus of our project is on the presence of PFAS in Long Island, which included water districts in both Nassau and Suffolk counties. The choice of this case study was prompted by the fact that the groundwater data was public and by lawsuits filed in November of 2019 against 3M Co., E.I. DuPont de Nemours and Co., and Chemours Co. for the alleged manufacturing, marketing, and selling of PFAS, despite environmental repercussions of these forever chemicals (see  here  and  here ).

In order to better understand the extent of PFAS contamination in Long Island’s groundwater, our team used publicly available data on PFAS in drinking water to map the concentration of PFAS in Long Island’s groundwater. Our data sources include the Third Unregulated Contaminant Monitoring Rule (UCMR3) reports, US Geological Survey (USGS) sample data and the PFAS concentrations reported in the water quality reports of utilities across Long Island.

About the Map

Maximum concentrations of PFAS compounds in parts per trillion (ppt) as measured in Long Island's drinking water sources.

The wells are mapped to the best of our abilities, given that information on the precise location of some of the wells is not available online.

Legend for the adjacent map

As is evident from the map above, PFAS are present throughout Long Island’s drinking water supply. The Rocky Point Pine Barrens State Forest region shows especially high level of PFAS concentrations. Note the North Road (Greenport)/Meetinghouse Road well in the centre of the map where unprecedented levels of PFAS were detected. The concentration values are in ppt.

To have a better understanding on what might be causing the presence of PFAS in the groundwater, we identified some of the potential sources where PFAS are (or were) used. These sources might include fire stations, airports, and military sites. A side-by-side map of PFAS detection and possible PFAS sources are presented in the following map.

The left map shows concentrations of PFAS measured and the right map shows potential sources that might be responsible for releasing PFAS into the environment.

Notable Regulatory Efforts

It is evident that PFAS are gaining political inertia at both the federal and state levels. A few examples of some noteworthy legal actions taken regarding PFAS contamination at the state and federal levels are presented in Table 1.

Awesome Table

References

ATSDR (Agency for Toxic Substances and Disease Recovery). (2020, June 24). PFAS chemical exposure | ATSDR. Agency for Toxic Substances and Disease Registry. https://www.atsdr.cdc.gov/pfas/health-effects/exposure.html

Dingell, D. (2020, January 13). H.R.535 - 116th Congress (2019-2020): PFAS Action Act of 2019 (2019/2020) [Webpage]. https://www.congress.gov/bill/116th-congress/house-bill/535

EEA (European Environment Agency). (2019, December 12). Emerging chemical risks in Europe — ‘PFAS’. European Environment Agency. https://www.eea.europa.eu/themes/human/chemicals/emerging-chemical-risks-in-europe

Hayes, P., & Gilmer, E. M. (2019, November 25). 3M, DuPont, Chemours hit with Long Island PFAS claims (1). Bloomberg Law.  https://news.bloomberglaw.com/product-liability-and-toxics-law/3m-dupont-chemours-hit-with-long-island-pfoa-claims 

NYS Assembly. (2019, December 23). New York State Assembly | Bill A00445A. https://nyassembly.gov/leg/?default_fld=&leg_video=&bn=A00445&term=2019&Summary=Y&Actions=Y&Memo=Y&Text=Y

NYS Assembly. (2020, January 7). NY State Assembly Bill A8979. NY State Senate. https://www.nysenate.gov/legislation/bills/2019/a8979

NYS DEC (Department of Environmental Conservation). (n.d.-a). Express Terms—6 NYCRR Part 597—NYS Dept. Of Environmental Conservation. Retrieved August 5, 2020, from http://www.dec.ny.gov/regulations/105074.html

NYS DEC. (n.d.-b). Per- and Polyfluoroalkyl Substances (PFAS)—NYS Dept. Of Environmental Conservation. Retrieved August 5, 2020, from https://www.dec.ny.gov/chemical/108831.html

NYS GPO (Governor’s Press Office). (2018, October 2). Governor Cuomo Announces $200 Million to Address Emerging Contaminants in Drinking Water. Governor Andrew M. Cuomo. https://www.governor.ny.gov/news/governor-cuomo-announces-200-million-address-emerging-contaminants-drinking-water

NYS GPO. (2020, July 30). Governor Cuomo Announces First in the Nation Drinking Water Standard for Emerging Contaminant 1,4-Dioxane. Governor Andrew M. Cuomo. https://www.governor.ny.gov/news/governor-cuomo-announces-first-nation-drinking-water-standard-emerging-contaminant-14-dioxane

NYS Senate. (2017a, April 4). NY State Senate Bill S2007B. NY State Senate. https://www.nysenate.gov/legislation/bills/2017/s2007/amendment/b

NYS Senate. (2017b, May 5). NY State Senate Bill S5902. NY State Senate. https://www.nysenate.gov/legislation/bills/2017/s5902

NYS Senate. (2019, June 11). NY State Senate Bill S439A. NY State Senate. https://www.nysenate.gov/legislation/bills/2019/s439/amendment/a

TFF (Toxic-Free Future). (2018, September 24). PFAS: A nonstick nightmare. Toxic-Free Future. https://toxicfreefuture.org/key-issues/chemicals-of-concern/pfas-nonstick-nightmare/

USEPA (United States Environmental Protection Agency). (2019, October 29). Basic information on PFAS. US EPA.  https://www.epa.gov/pfas/basic-information-pfas 

USEPA, OCSPP (Office of Chemical Safety and Pollution Prevention). (2016, May 10). Fact Sheet: 2010/2015 PFOA Stewardship Program [Collections and Lists]. US EPA. https://www.epa.gov/assessing-and-managing-chemicals-under-tsca/fact-sheet-20102015-pfoa-stewardship-program

USEPA, OW (Office of Water). (2016, May 5). Drinking Water Health Advisories for PFOA and PFOS [Overviews and Factsheets]. US EPA. https://www.epa.gov/ground-water-and-drinking-water/drinking-water-health-advisories-pfoa-and-pfos

Woyton, M. (2019, May 10). Toxic PFAS chemical found on Long Island — Here's where. Westhampton-Hampton Bays, NY Patch.  https://patch.com/new-york/westhampton-hamptonbays/toxic-pfas-chemical-found-long-island-here-s-where 

Zhao, B., Lian, Q., Chu, Y., Hardy, D. O., Li, X., & Ge, R. (2011). The inhibition of human and rat 11β-hydroxysteroid dehydrogenase 2 by perfluoroalkylated substances. The Journal of Steroid Biochemistry and Molecular Biology125(1-2), 143-147.  https://doi.org/10.1016/j.jsbmb.2010.12.017 

Any questions, comments, concerns about the project can be directed to either Harman Singh Dhodi (hd353@cornell.edu) or Julia Gonzales (jeg334@cornell.edu).

Harman Singh Dhodi

2020 Intern at NYSWRI

Caroline Smith

2020 Intern at NYSWRI

Rassil Sayess

Research and Outreach Specialist at NYSWRI

Legend for the adjacent map