An image of a stream with vegetation on its banks and mountains in the distance.

The Rocky Road to a Healthier River:

Salts, Chemical Cocktails, and a Path Forward

Introduction

America’s waterways – the rivers, streams, and tributaries that run through our communities – all contain natural salts and minerals. Through human activities and the development of gray infrastructure (roads, buildings, sidewalks), many waterways experience a dramatic increase in both salt and metal concentrations.

A stream with a sandy bank surrounded by vegetation and trees.
A stream with a sandy bank surrounded by vegetation and trees.

Human activities - including road salt application, sewage leaks, water softening, detergent use, mining and oil production, commercial and industrial processes, weathering of concrete, sea level rise, and fertilizer application – all contribute to the rise in salts and metals in our waterways.

Infographic displaying sources of introduced salts to the environment. The title of the graphic is Salt Sources in the Environment and lists these sources as 1) Road Salt & Concrete Weathering, 2) Agricultural Practices & Fertilizers, 3) Wastewater Treatment Plants, 4) Mining & Oil Production, and 5) Detergents & Water Softeners.
Infographic displaying sources of introduced salts to the environment. The title of the graphic is Salt Sources in the Environment and lists these sources as 1) Road Salt & Concrete Weathering, 2) Agricultural Practices & Fertilizers, 3) Wastewater Treatment Plants, 4) Mining & Oil Production, and 5) Detergents & Water Softeners.

Increased salinity in our waterways is impacting both environmental and human health. Higher levels of salt can harm aquatic life, including fish and plants, by increasing the concentrations of heavy metals and other pollutants in waterways. It is also a risk to humans. Winter salts can cause illness if ingested and saltier drinking water is a risk for people with low salt diets.

Infographic explaining that salts are a risk to human health and the health of pets, wildlife, and plants. The title is Health Risks, with a Subheading for Pets & Wildlife that explains Winter salts can make your pets sick or irritate their paws, while saltier waters can negatively impact wild animals, fish, and plants. The second Subheading is Humans and explains Winter salts can make children sick if they ingest it, while saltier waters can increase risks for people with health conditions like high blood pressure.

Additionally, saltier water can damage critical infrastructure, including bridges and drinking water systems. It can also damage private infrastructure including vehicles, household appliances, and landscaping.

Infographic explaining that salts are a risk to both public and private infrastructure. The title is Infrastructure Risks with a subheading of Public Infrastructure that says Winter salts and saltier waters can damage infrastructure related to transportation, as well as stormwater and drinking water management. The second subheading says Private Infrastructure and explains Winter salts can also damage your vehicles, household appliances, and landscaping.

Researching Chemical Cocktails

We investigated how concentrations of salts play a role in mobilizing metals and other pollutants into our rivers and streams. Our research is intended to improve our understanding of chemical cocktails in our waterways and to better manage our water quality. 

Researcher descends streambank to collect water quality data next to a road.
EPA researcher collect water quality data in a stream.
Researcher collects water sample for laboratory analysis.

Our research focused on five cities, sampling along different rivers and streams to analyze the presence of specific salts and chemical cocktails. This approach helped us to understand how salt and chemical concentrations in the waterways shifted downstream as they moved through developed land and/or green spaces.

Depending on how land is being used, various salts, nutrients, metals, and organic matter end up being "mixed together" to create unique "chemical cocktails". These cocktails enter our waterways and build up over time, combining and compounding upon one another.

Infographic that showcases how different salts, metals, organic matter, and nutrients combine to create unique chemical cocktails. The infographic showcases that different land uses, such as urban, agriculture, or recreation, produce different chemical cocktails that accumulate in a waterway together over time and space. The title is Chemical Cocktails and the infographic explains that depending on how land is being used, various salts, nutrients, metals, and organic matter end up being "mixed together" to creature unique "chemical cocktails". These cocktails enter our waterways and over time different chemical cocktails build up in the waterway, combining and compounding upon one another.
Infographic that showcases how different salts, metals, organic matter, and nutrients combine to create unique chemical cocktails. The infographic showcases that different land uses, such as urban, agriculture, or recreation, produce different chemical cocktails that accumulate in a waterway together over time and space. The title is Chemical Cocktails and the infographic explains that depending on how land is being used, various salts, nutrients, metals, and organic matter end up being "mixed together" to creature unique "chemical cocktails". These cocktails enter our waterways and over time different chemical cocktails build up in the waterway, combining and compounding upon one another.

Our research focused on answering:

  • Are salt concentrations elevated in cities across the U.S.?
  • Do distinct mixtures of salts and metals relate to different kinds of land use and human activities?
  • Can green space (such as stream restoration, parks, and conservation areas) reduce salt concentrations?

Site Details

Sampling occurred along nine rivers and streams, spanning five different U.S. metropolitan areas, including:

  1. Baltimore, Maryland: Scotts Level Branch and Gwynns Falls
  2. Washington, D.C.: Northwest Branch - Anacostia River, Watts Branch, and Bull Run
  3. Cincinnati, Ohio: Licking River
  4. Denver, Colorado: Boulder Creek and the South Platte River
  5. Portland, Oregon: Willamette River

Waterways in these cities experience variations in climate, land use, underlying geology, and watershed size.

In order to test if any chemical cocktails are common across cities, we compared four major ingredients of chemical cocktails - major ions, metals, nutrients, and organic matter - within and across these streams.

Baltimore, Maryland

Image of Gwynns Falls waterway with residences in the background.

Gwynns Falls

Baltimore, Maryland

Image of Scotts Level Branch with winter landscape and dried vegetative streambanks.

Scotts Level Branch

Washington, DC

Image of Anacostia River with rocky streambanks and whitewater flowing.

Northwest Branch - Anacostia

Washington, DC

Image of Bull Run with full green foliage and vegetated streambanks.

Bull Run

Washington, DC

Image of a natural dam in Watts Branch.

Watts Branch

Cincinnati, Ohio

Image of Licking River in winter with snow on the banks.

Licking River

Denver, Colorado

Image of South Platte River passing through Denver Colorado with bridge in background and community plaza on the bank.

South Platte River

Denver, Colorado

Snowy overhead image of Boulder Creek.

Boulder Creek

Portland, Oregon

Image of bridge and industry underneath crossing over Willamette River.

Willamette River

In doing so, we discovered that with...

An infographic showcasing that various land uses, including urbanization, lead to increasingly salty chemical cocktail concentrations in waterways. The graphic's title is Urbanization and it points our Portland Oregon, Denver Colorado, Cincinnati Ohio, Washington D.C., and Baltimore Maryland on the map. It summarizes that with increasing urbanization there is a trend of increasing salty chemical cocktail concentrations. A subheading titled What We Found explains that concentrations of salty chemical cocktails increased as water flowed through increasingly urbanized areas without significant green spaces.

In waterways that flow through increasingly urbanized areas (Boulder Creek, South Platte River, Licking River, Bull Run, Watts Branch, and Willamette River) the salty chemical cocktails increased in concentration alongside increasing degrees of urbanization.

These elevated salt concentrations suggest that freshwater salinization can occur in urbanized streams in different parts of the U.S.

Boulder Creek

A snowy portion of Boulder Creek with residences seen through the trees.

South Platte River

A snowy bank of the South Platter River in Denver, Colorado with infrastructure and roads.

Licking River

A portion of the Licking River in Cincinnati, Ohio with a bridge crossing in focus.

Bull Run

Watts Branch

Willamette River

The infographic has a title Green Spaces and highlights Washington D.C. and Baltimore Maryland on the map. It summarizes that green spaces are found to manage concentrations of salts and chemical cocktails in waterways, stabilizing or decreasing them as water moves through. It includes a subheading What We Found that explains concentrations of salty chemical cocktails either decreased or stabilized as water flowed through green spaces (parks, conservation and restoration areas, forests).

Although we generally observed increasing salinity and chemical cocktails in cities , there were three streams with decreasing or stable trends as they flowed through parks and restoration areas (Scotts Level Branch, Northwest Branch - Anacostia River, and Gwynns Falls).

These findings suggest that parks, conservation areas, forest cover and other natural features may protect waterways from the urban impacts of salinization and reduce pollutant mobilization observed in other sampling locations.   

Northwest Anacostia

A portion of the Northwest Branch of the Anacostia River in Washington, D.C. with vegetation on its banks showcasing fall foliage.

Gwynns Falls

A portion of Gwynns Falls, showcasing a rocky streambank with vegetation on the sides.

Scotts Level Branch

(Restoration Project)

A stream restoration projects at Scotts Level Branch in Baltimore, MD. The banks of the stream actively under reconstruction to restore native vegetation and improve water quality.

Summary

Our research showed that we can anticipate increasing concentrations of salty chemical cocktails in rivers as they flow through more urban areas. The elevated concentration of salty chemical cocktails in urbanized areas suggests that this is a common attribute of waterways that move through our cities and suburbs. Conservation areas, forest cover, and other natural features or practices that manage stormwater flow may prevent the impacts of salinization and pollutant mobilization observed in more urbanized areas.

These results showcase how land use plays a role in the movement of salts and chemical cocktails into our waterways, and of the potential for point and nonpoint source pollution management in addressing salinization and freshwater quality in our communities.

The full details of this research are available in the peer-reviewed paper " Salty chemical cocktails as water quality signatures: Longitudinal trends and breakpoints along different U.S. streams "  {EXIT}  available in the journal, Science of the Total Environment.

Significance

Increasingly salty waterways – and those with increased concentrations of chemical cocktails – pose a risk to the health of our freshwater systems, to our drinking water infrastructure, and to our public health.

To better manage the health of our waterways, studies like these point to potential solutions that address freshwater salinization and manage concentrations in our waterways. As this research suggests, green spaces – parks, conservation areas, forested zones – and other stormwater management practices can prove to be valuable tools in support of salinization management.

What can you do?

Once salt enters our environment it becomes challenging to remove it in an effective way. In order to address the risks freshwater salinization poses to the environment, our human health, and the built infrastructure, a multi-faceted approach involving community, municipal, and private partners is required. Our response to these risks need be based on sound science and effective management techniques, with a focus on a holistic approach to decrease salt use and minimize its pathways into our waterways.

There are a number of ways that you can play a part in this:

Resources for Individuals

Practice smart winter salt use:

  • Shovel walkways and driveways regularly and when possible, before snow turns to ice
  • Use just enough salt required to melt the snow or ice, and only in the right conditions
  • Use alternatives, like sand, for traction and to reduce salt use
  •  Learn more about smart salt application practices   {EXIT} 

Protect your family:

  • Keep kids (and yourselves) from ingesting snow – especially any that may have had contact with road salts, deicers, or other potentially harmful applications
  • Keep your pets' paws secure on winter walks, and minimize any potential ingestion of contaminated water or soil

Get Involved:

  • Learn what steps your local government may be taking towards more responsible salt management policies
  • Explore whether salt watch programs and pledges exist for your community to develop best practices through
  •  Connect with your elected officials  {EXIT} 

Resources for Municipal and Government Leaders

An image of a stream with vegetation on its banks and mountains in the distance.

 Contact Us  to ask a question, provide feedback, or report a problem.

EPA Region 3, Water Division, State and Partnerships Branch

Gwynns Falls

Scotts Level Branch

Northwest Branch - Anacostia

Bull Run

Watts Branch

Licking River

South Platte River

Boulder Creek

Willamette River